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Paper Details

Induced Electron Transfer in Pentaamminecobalt (III) Complexes of ?-Amino Acids by Mn(III)perchlorate in Micellar Medium

Subramanian Udhayavani

Journal Title:Journal of Chemical, Biological and physical sciences
Abstract


Oxidation of pentaamminecobalt (III) complexes of ?-amino acids by Mn(III)perchlorate in micellar medium yielding nearly 100% of carbonyl compounds are ultimate products. The decrease in UV-Visible absorbance at ?=502nm for Co(III) complex corresponds to nearly 100% of the initial absorbance. The synchronous C-C bond fission and electron transfer of Co(III) centre. In addition, we have determined the micelle concentration of the surfactant-cobalt (III) complex and studied the kinetics of the complex with Mn(III)perchlorate. It has been found the rate of oxidation of Co(III) complexes of unbound and bound moieties are enhanced more in the presence of CTAB when compare to the NaLS.

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