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Paper Details

Induced electron transfer reaction of Cobalt (III) complexes by imidazolinium dichromate in the presence of surfactant medium

B.Mohammed Nawaz K.Subramani and A.Nazim Ahmed

Journal Title:Journal of Chemical, Biological and physical sciences
Abstract


The kinetics of one electron transfer route seems to be unavailable for IDC with Cobalt (III) bound and unbound complexes of ?-hydroxyacid in micellar medium, IDC oxidizes Cobalt(III) bound and unbound ?-hydroxyacids. It rules out the synchronousC-C bond fission and electron transfer to Cobalt (III) centre. Oxidation of above complexes increases with increase of temperature. With increase in micellar concentration an increase in the rate is observed. The added TTAB enhances the rate of oxidation of a reaction much more than NaLS. Similar trends has been observed in lactato and glycolato Co (III) complexes

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