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Paper Details

ZnII, CdII and HgII complexes with N-(morpholinomethyl) phthalimide as a new Mannich base ligand: Synthesis, Characterization and Antimicrobial studies

L. Muruganandam1*, K.Balasubramanian1, M. Ramesh2, and A. Sebastiyan3

Journal Title:Journal of Chemical, Biological and physical sciences

The new Mannich base N-(morpholinomethyl)phthalimide(MMP) was prepared by the Mannich synthetic route of morpholine, formaldehyde and Phthalimide. The d10 transition metal complexes with this ligand were synthesized and have been characterized on the basis of elemental analysis, molar conductance, UV-Visible, IR and NMR spectral studies. The bidentate chelation of MMP, bonding through carbonyl oxygen of imide moiety and CNC of morpholine ring is suggested. Based on the IR and 1H NMR studies octahedral geometry is assigned for all the complexes. The ligand and complexes have been screened for their antibacterial and antifungal activities.