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Paper Details

Intermolecular Inter-ligand Interaction in Mixed Ligand Complexes of Lanthanoids (lII) Involving CDTA and Some O-N donor Amino Acids

Vivek Tiwari* and Rashmi Singhai**

Journal Title:Journal of Chemical, Biological and physical sciences
Abstract


The formnation constant studies on binary (log K) and mixed ligand complexes (log K) and stability quantifying parameters (log k and ?? log k) to examine the extra-stabilization due to inter-ligand interaction in Pr (lll) and Nd(lII) complexes involving cyclohexanediaminetetraaceticacid (CDTA ) as primary ligand and a-alanine (a-ala), valine (val) or leucine (leu) as secondary ligands have been undertaken to evaluate the possible occurrence of intramolecular inter-ligand interaction. Stability quantifying parameters (? log k and ?? log k) indicates significant inter-ligand interaction.

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